air

The Earth's atmosphere (or air) is a layer of gases surrounding the planet Earth that is retained by the Earth's gravity. Dry air contains roughly (by volume) 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.038% carbon dioxide, and trace amounts of other gases. Air also contains a variable amount of water vapor, on average around 1%. The atmosphere protects life on Earth by absorbing ultraviolet solar radiation, warming the surface through heat retention (greenhouse effect), and reducing temperature extremes between day and night.

There is no definite boundary between the atmosphere and outer space. It slowly becomes thinner and fades into space. An altitude of 120 km (75 mi) marks the boundary where atmospheric effects become noticeable during reentry. The Kármán line, at 100 km (62 mi), is also frequently regarded as the boundary between atmosphere and outer space. Three quarters of the atmosphere's mass is within 11 km (6.8 mi; 36,000 ft) of the surface.
The temperature of the Earth's atmosphere varies with altitude; the mathematical relationship between temperature and altitude varies among five different atmospheric layers (ordered highest to lowest, the ionosphere is part of the thermosphere):

Exosphere
From 500–1,000 km (310–620 mi) up to 10,000 km (6,200 mi), contain free-moving particles that may migrate into and out of the magnetosphere or the solar wind.
Exobase
Also known as the critical level, it is the lower boundary of the exosphere.
Ionosphere
The part of the atmosphere that is ionized by solar radiation stretches from 50 to 1,000 km (31 to 620 mi) and typically overlaps both the exosphere and the thermosphere. It plays an important part in atmospheric electricity and forms the inner edge of the magnetosphere. Because of it's charged particles, it has practical importance because it influences, for example, radio propagation on the Earth. It is responsible for auroras.
Thermopause
The boundary above the thermosphere, it varies in height from 500–1,000 km (310–620 mi).
Thermosphere
From 80–85 km (50–53 mi; 260,000–280,000 ft) to over 640 km (400 mi; 2,100,000 ft), temperature increasing with height. Although the temperature can rise to 1,500 °C (2,730 °F), a person would not feel warm because of the extreme low pressure. The International Space Station orbits in this layer, between 320 and 380 km (200 and 240 mi).
Mesopause
The temperature minimum at the boundary between the thermosphere and the mesosphere. It is the coldest place on Earth, with a temperature of −100 °C (−148.0 °F; 173.1 K).
Mesosphere
From the Greek word "μέσος" meaning middle. The mesosphere extends from about 50 km (31 mi; 160,000 ft) to the range of 80–85 km (50–53 mi; 260,000–280,000 ft). Temperature decreases with height, reaching −100 °C (−148.0 °F; 173.1 K) in the upper mesosphere. This is also where most meteors burn up when entering the atmosphere.
Stratopause
The boundary between the mesosphere and the stratosphere, typically 50 to 55 km (31 to 34 mi; 160,000 to 180,000 ft). The pressure here is 1/1000th sea level.
Stratosphere
From the Latin word "stratus" meaning spreading out. The stratosphere extends from the troposphere's 7–17 km (4.3–11 mi; 23,000–56,000 ft) range to about 51 km (32 mi; 170,000 ft). Temperature increases with height. The stratosphere contains the ozone layer, the part of the Earth's atmosphere which contains relatively high concentrations of ozone. "Relatively high" means a few parts per million—much higher than the concentrations in the lower atmosphere but still small compared to the main components of the atmosphere. It is mainly located in the lower portion of the stratosphere from approximately 15–35 km (9.3–22 mi; 49,000–110,000 ft) above Earth's surface, though the thickness varies seasonally and geographically.
Ozone Layer
Though part of the Stratosphere, the ozone layer is considered as a layer of the Earth in itself due to the fact that its physical and chemical composition is far different to the Stratosphere. Ozone in the earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O2 to create ozone, O3. The ozone molecule is also unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O2 and an atom of atomic oxygen, a continuing process called the ozone-oxygen cycle, thus creating an ozone layer in the stratosphere, the region from about 10 to 50 km (33,000 to 160,000 ft) above Earth's surface. About 90% of the ozone in our atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about 20 and 40 km (66,000 and 130,000 ft), where they range from about 2 to 8 parts per million.
Tropopause
The boundary between the stratosphere and troposphere.
Troposphere
From the greek word "τρέπω" meaning to turn or change. The troposphere is the lowest layer of the atmosphere; it begins at the surface and extends to between 7 km (23,000 ft) at the poles and 17 km (56,000 ft) at the equator, with some variation due to weather factors. The troposphere has a great deal of vertical mixing because of solar heating at the area. This heating makes air masses less dense so they rise. When an air mass rises, the pressure upon it decreases so it expands, doing work against the opposing pressure of the surrounding air. To do work is to expend energy, so the temperature of the air mass decreases. As the temperature decreases, water vapor in the air mass may condense or solidify, releasing latent heat that further uplifts the air mass. This process determines the maximum rate of decline of temperature with height, called the adiabatic lapse rate. The troposphere contains roughly 80% of the total mass of the atmosphere. Fifty percent of the total mass of the atmosphere is located in the lower 5.6 km (18,000 ft) of the troposphere.

The average temperature of the atmosphere at the surface of Earth is 20 °C (68 °F; 293 K).[1][2]

[edit] Pressure and thickness

Main article: Atmospheric pressure

The average atmospheric pressure, at sea level, is about 101.3 kilopascals (14.69 psi); total atmospheric mass is 5.1480×1018 kg (1.135×1019 lb).[3]

Atmospheric pressure is a direct result of the total weight of the air above the point at which the pressure is measured. Air pressure varies with location and time, because the amount (and weight) of air above the earth varies with location and time. However, the average mass of the air above a square meter of the Earth's surface can be calculated from the total amount of air and the surface area of the Earth. The total air mass is 5148.0 teratonnes and area is 51007.2 megahectares. Thus 5148.0/510.072 = 10.093 tonnes (9.934 LT; 11.126 ST) per square meter or 14.356 pounds per square inch (98.98 kPa). This is about 2.5% below the officially standardized unit atmosphere (1 atm) of 101.325 kPa or 14.696 psi, and corresponds to the mean pressure not at sea level, but at the mean base of the atmosphere as contoured by the Earth's terrain.

Were atmospheric density to remain constant with height the atmosphere would terminate abruptly at 7.81 km (25,600 ft). Instead, density decreases with height, dropping by 50% at an altitude of about 5.6 km (18,000 ft). For comparison the highest mountain, Mount Everest, is higher, at 8.8 km (29,000 ft), so air is less than half as dense at the summit than at sea level. This is why it is so difficult to climb without supplemental oxygen.

This pressure drop is approximately exponential, so that pressure decreases by approximately half every 5.6 km (18,000 ft) and by 63.2% (1 − 1 / e = 1 − 0.368 = 0.632) every 7.64 km (25,100 ft), the average scale height of Earth's atmosphere below 70 km (43 mi; 230,000 ft). However, because of changes in temperature, average molecular weight, and gravity throughout the atmospheric column, the dependence of atmospheric pressure on altitude is modeled by separate equations for each of the layers listed above. Even in the exosphere, the atmosphere is still present. This can be seen by the effects of atmospheric drag on satellites.

In summary, the equations of pressure by altitude in the above references can be used directly to estimate atmospheric thickness. However, the following published data are given for reference:[4]

* 50% Of the atmosphere by mass is below an altitude of 5.6 km (18,000 ft).
* 90% Of the atmosphere by mass is below an altitude of 16 km (52,000 ft). The common altitude of commercial airliners is about 10 km (33,000 ft) and Mt. Everest's summit is 8,848 m (29,030 ft) above sea level.
* 99.99997% Of the atmosphere by mass is below 100 km (62 mi; 330,000 ft). The highest X-15 plane flight in 1963 reached an altitude of 354,300 ft (108.0 km). Therefore, most of the atmosphere (99.9997%) is below 100 km (62 mi; 330,000 ft), although in the rarefied region above this there are auroras and other atmospheric effects.

[edit] Composition

Main article: Atmospheric chemistry

Composition of Earth's atmosphere as of Dec. 1987. The lower pie represents the least common gases that compose 0.038% of the atmosphere. Values normalized for illustration.

Filtered air includes trace amounts of many of the chemical elements. Substantial amounts of argon, nitrogen, and oxygen are present as elementary gases. Note the major greenhouse gasses: water vapor, carbon dioxide, methane, nitrous oxide, and ozone. Many additional elements from natural sources may be present in tiny amounts in an unfiltered air sample, including contributions from dust, pollen and spores, sea spray, vulcanism, and meteoroids. Various industrial pollutants are also now present in the air, such as chlorine (elementary or in compounds), fluorine (in compounds), elementary mercury, and sulfur (in compounds such as sulfur dioxide [SO2])